The ECU is covered in conformal coating to protect it from corrosion and moisture.
It's starting to peel off but it's no big deal.
You could if you had a lot of time and patience, take to it with some acetone and a toothbrush but you just need to be careful you don't damage anything on the 20+yo board while you're doing it (only do the underside).
Just so you know, the whole board is covered in it... I would probably just concentrate on the areas in the last 4 pics and leave it at that.
If you want to recoat, idk if you can just use clear paint but Jack has obviously tested it out.